2,028 research outputs found
The Structure and C=C Vibrational Frequencies of the all- trans Polyenes C2nH2n+2(n=2-15), C2nH2n(Me)2(n=2-13), and C2nH2n(tert-Butyl)2(n=2-5): Computational Results
Carbon-carbon bond lengths and C=C vibrational frequencies are reported for the linear, all-trans unsubstituted C2nH2n+2 (n=2-15), methyl capped C2nH2nMe2 (n=2-13), and tert-butyl capped C2nH2n(tert-butyl)2 (n=2-5) polyenes (C2h) calculated at the B3LYP/6-311++G(d,p) level. The C=C/C-C bond length alternation remains evident at this level for the unsubstituted and methyl capped polyenes as the chain length increases; the center-most difference in the length of the C-C/C=C bonds is ~0.06 AÌ for C30H32 and C26H26Me2. The Ag, in-phase, harmonic C=C Raman frequency for the unsubstituted polyenes decreases from 1699.2 cm-1 (n = 2) to 1528.9 cm-1 (n=15); the anharmonic frequency decreases from 1651.5 cm-1 (n = 2) to 1547.7 cm-1 (n = 8). The harmonic C=C frequency for the methyl capped polyenes decreases from 1717.9 cm-1 (n = 2) to 1539.6 cm- 1 (n= 13), and the anharmonic C=C frequency decreases from 1675.0 cm-1 (n = 2) to 1562.8 cm-1 (n = 7)
Radial HI Profiles at the Periphery of Galactic Disks: The Role of Ionizing Background Radiation
Observations of neutral hydrogen in spiral galaxies reveal a sharp cutoff in
the radial density profile at some distance from the center. Using 22 galaxies
with known HI distributions as an example, we discuss the question of whether
this effect can be associated exclusively with external ionizing radiation, as
is commonly assumed. We show that before the surface density reaches
(the same for
galaxies of different types), it is hard to expect the gas to be fully ionized
by background radiation. For two of 13 galaxies with a sharp drop in the HI
profile, the "steepening" can actually be caused by ionization. At the same
time, for the remaining galaxies, the observed cutoff in the radial HI profile
is closer to the center than if it was a consequence of ionization by
background radiation and, therefore, it should be caused by other factors.Comment: 15 pages, 6 figure
A Dust-Penetrated Classification Scheme for Bars as Inferred from their Gravitational Force Fields
The division of galaxies into ``barred'' (SB) and ``normal'' (S) spirals is a
fundamental aspect of the Hubble galaxy classification system. This ``tuning
fork'' view was revised by de Vaucouleurs, whose classification volume
recognized apparent ``bar strength'' (SA, SAB, SB) as a continuous property of
galaxies called the ``family''. However, the SA, SAB, and SB families are
purely visual judgments that can have little bearing on the actual bar strength
in a given galaxy. Until very recently, published bar judgments were based
exclusively on blue light images, where internal extinction or star formation
can either mask a bar completely or give the false impression of a bar in a
nonbarred galaxy. Near-infrared camera arrays, which principally trace the old
stellar populations in both normal and barred galaxies, now facilitate a
quantification of bar strength in terms of their gravitational potentials and
force fields. In this paper, we show that the maximum value, Qb, of the ratio
of the tangential force to the mean radial force is a quantitative measure of
the strength of a bar. Qb does not measure bar ellipticity or bar shape, but
rather depends on the actual forcing due to the bar embedded in its disk. We
show that a wide range of true bar strengths characterizes the category ``SB'',
while de Vaucouleurs category ``SAB'' corresponds to a much narrower range of
bar strengths. We present Qb values for 36 galaxies, and we incorporate our bar
classes into a dust-penetrated classification system for spiral galaxies.Comment: Accepted for publication in the Astrophysical Journal (LaTex, 30
pages + 3 figures); Figs. 1 and 3 are in color and are also available at
http://bama.ua.edu/~rbuta/bars
The Dwarf Galaxy Population of the Dorado group down to Mv=-11
We present V and I CCD photometry of suspected low-surface brightness dwarf
galaxies detected in a survey covering ~2.4 deg^2 around the central region of
the Dorado group of galaxies. The low-surface brightness galaxies were chosen
based on their sizes and magnitudes at the limiting isophote of 26.0V\mu. The
selected galaxies have magnitudes brighter than V=20 (Mv=-11 for an assumed
distance to the group of 17.2 Mpc), with central surface brightnesses \mu0>22.5
V mag/arcsec^2, scale lengths h>2'', and diameters > 14'' at the limiting
isophote. Using these criteria, we identified 69 dwarf galaxy candidates. Four
of them are large very low-surface brightness galaxies that were detected on a
smoothed image, after masking high surface brightness objects. Monte Carlo
simulations performed to estimate completeness, photometric uncertainties and
to evaluate our ability to detect extended low-surface brightness galaxies show
that the completeness fraction is, on average, > 80% for dwarf galaxies with
and 22.5<\mu0<25.5 V mag/arcsec^2, for the range of sizes
considered by us (D>14''). The V-I colors of the dwarf candidates vary from
-0.3 to 2.3 with a peak on V-I=0.98, suggesting a range of different stellar
populations in these galaxies. The projected surface density of the dwarf
galaxies shows a concentration towards the group center similar in extent to
that found around five X-ray groups and the elliptical galaxy NGC1132 studied
by Mulchaey and Zabludoff (1999), suggesting that the dwarf galaxies in Dorado
are probably physically associated with the overall potential well of the
group.Comment: 32 pages, 16 postscript figures and 3 figures in GIF format, aastex
v5.0. To appear in The Astronomical Journal, January 200
Semi-Analytical Models for Lensing by Dark Halos: I. Splitting Angles
We use the semi-analytical approach to analyze gravitational lensing of
quasars by dark halos in various cold dark matter (CDM) cosmologies, in order
to determine the sensitivity of the prediction probabilities of images
separations to the input assumptions regarding halos and cosmologies. The mass
function of dark halos is assumed to be given by the Press-Schechter function.
The mass density profile of dark halos is alternatively taken to be the
singular isothermal sphere (SIS), the Navarro-Frenk-White (NFW) profile, or the
generalized NFW profile. The cosmologies include: the Einstein-de Sitter model
(SCDM), the open model (OCDM), and the flat \Lambda-model (LCDM). As expected,
we find that the lensing probability is extremely sensitive to the mass density
profile of dark halos, and somewhat less so to the mean mass density in the
universe, and the amplitude of primordial fluctuations. NFW halos are very much
less effective in producing multiple images than SIS halos. However, none of
these models can completely explain the current observations: the SIS models
predict too many large splitting lenses, while the NFW models predict too few
small splitting lenses. This indicates that there must be at least two
populations of halos in the universe. A combination of SIS and NFW halos can
reasonably reproduce the current observations if we choose the mass for the
transition from SIS to NFW to be ~ 10^{13} solar masses. Additionally, there is
a tendency for CDM models to have too much power on small scales, i.e. too much
mass concentration; and it appears that the cures proposed for other apparent
difficulties of CDM would help here as well, an example being the warm dark
matter (WDM) variant which is shown to produce large splitting lenses fewer
than the corresponding CDM model by one order of magnitude.Comment: 46 pages, including 13 figures. Revised version with significant
improvemen
Climate risk management for water in semi-arid regions
Background: New sources of hydroclimate information based on forecast models and observational data have the potential to greatly improve the management of water resources in semi-arid regions prone to drought. Better management of climate-related risks and opportunities requires both new methods to develop forecasts of drought indicators and river flow, as well as better strategies to incorporate these forecasts into drought, river or reservoir management systems. In each case the existing institutional and policy context is key, making a collaborative approach involving stakeholders essential.
Methods: This paper describes work done at the IRI over the past decade to develop statistical hydrologic forecast and water allocation models for the semi arid regions of NE Brazil (the âNordesteâ) and central northern Chile based on seasonal climate forecasts.
Results: In both locations, downscaled precipitation forecasts based on lagged SST predictors or GCM precipitation forecasts exhibit quite high skill. Spring-summer melt flow in Chile is shown to be highly predictable based on estimates of previous winter precipitation, and moderately predictable up to 6 months in advance using climate forecasts. Retrospective streamflow forecasts here are quite effective in predicting reductions in water rights during dry years. For the multi-use Oros reservoir in NE Brazil, streamflow forecasts have the most potential to optimize water allocations during multi-year low-flow periods, while the potential is higher for smaller reservoirs, relative to demand.
Conclusions: This work demonstrates the potential value of seasonal climate forecasting as an integral part of drought early warning and for water allocation decision support systems in semi-arid regions. As human demands for water rise over time this potential is certain to rise in the future
UV-Optical Pixel Maps of Face-On Spiral Galaxies -- Clues for Dynamics and Star Formation Histories
UV and optical images of the face-on spiral galaxies NGC 6753 and NGC 6782
reveal regions of strong on-going star formation that are associated with
structures traced by the old stellar populations. We make NUV--(NUV-I) pixel
color-magnitude diagrams (pCMDs) that reveal plumes of pixels with strongly
varying NUV surface brightness and nearly constant I surface brightness. The
plumes correspond to sharply bounded radial ranges, with (NUV-I) at a given NUV
surface brightness being bluer at larger radii. The plumes are parallel to the
reddening vector and simple model mixtures of young and old populations, thus
neither reddening nor the fraction of the young population can produce the
observed separation between the plumes. The images, radial surface-brightness,
and color plots indicate that the separate plumes are caused by sharp declines
in the surface densities of the old populations at radii corresponding to disk
resonances. The maximum surface brightness of the NUV light remains nearly
constant with radius, while the maximum I surface brightness declines sharply
with radius. An MUV image of NGC 6782 shows emission from the nuclear ring. The
distribution of points in an (MUV-NUV) vs. (NUV-I) pixel color-color diagram is
broadly consistent with the simple mixture model, but shows a residual trend
that the bluest pixels in (MUV-NUV) are the reddest pixels in (NUV-I). This may
be due to a combination of red continuum from late-type supergiants and [SIII]
emission lines associated with HII regions in active star-forming regions. We
have shown that pixel mapping is a powerful tool for studying the distribution
and strength of on-going star formation in galaxies. Deep, multi-color imaging
can extend this to studies of extinction, and the ages and metallicities of
composite stellar populations in nearby galaxies.Comment: LaTeX with AASTeX style file, 29 pages with 12 figures (some color,
some multi-part). Accepted for publication in The Astrophysical Journa
The Opacity of Spiral Galaxy Disks VI: Extinction, stellar light and color
In this paper we explore the relation between dust extinction and stellar
light distribution in disks of spiral galaxies. Extinction influences our
dynamical and photometric perception of disks, since it can distort our
measurement of the contribution of the stellar component. To characterize the
total extinction by a foreground disk, Gonzalez et al. (1998) proposed the
``Synthetic Field Method'' (SFM), which uses the calibrated number of distant
galaxies seen through the foreground disk as a direct indication of extinction.
The method is described in Gonzalez et al. (1998) and Holwerda et al. (2005a).
To obtain good statistics, the method was applied to a set of HST/WFPC2 fields
Holwerda et al. (2005b) and radial extinction profiles were derived, based on
these counts. In the present paper, we explore the relation of opacity with
surface brightness or color from 2MASS images, as well as the relation between
the scalelengths for extinction and light in the I band. We find that there is
indeed a relation between the opacity (A_I) and the surface brightness,
particularly at the higher surface brightnesses. No strong relation between
near infrared (H-J, H-K) color and opacity is found. The scalelengths of the
extinction are uncertain for individual galaxies but seem to indicate that the
dust distribution is much more extended than the stellar light. The results
from the distant galaxy counts are also compared to the reddening derived from
the Cepheids light-curves Freedman et al. (2001). The extinction values are
consistent, provided the selection effect against Cepheids with higher values
of A_I is taken into account. The implications from these relations for disk
photometry, M/L conversion and galaxy dynamical modeling are briefly discussed.Comment: 9 pages, 2 tables, 10 figures, accepted by A&
Dynamic Fluctuation Phenomena in Double Membrane Films
Dynamics of double membrane films is investigated in the long-wavelength
limit including the overdamped squeezing mode. We demonstrate that thermal
fluctuations essentially modify the character of the mode due to its nonlinear
coupling to the transversal shear hydrodynamic mode. The corresponding Green
function acquires as a function of the frequency a cut along the imaginary
semi-axis. Fluctuations lead to increasing the attenuation of the squeezing
mode it becomes larger than the `bare' value.Comment: 7 pages, Revte
The time-dependent localization of Ki 67 antigen-positive cells in human skin wounds
A total of 77 human skin wounds with a post-infliction interval between 3 h and 7 months were investigated and the proliferation marker antigen Ki 67 was visualized in paraffin sections using a specific monoclonal antibody (MIB). The re-built epidermal layer covering the former lesional area showed only a few basal cells positively staining for Ki 67 antigen. No enhanced reactivity was found when compared to uninjured skin. In basal cells of the epidermis adjacent to the wound area, however, varying numbers of positive cells occurred, but no information useful for a reliable time estimation of skin wounds could be obtained due to the considerable variability in the number of Ki 67 positive epidermal basal cells found in non-damaged skin. Fibroblastic cells in the wound area revealed an increased number of Ki 67-positive sites which could first be detected in a 1.5-day-old skin lesion. Positive results could be obtained in every specimen investigated after a post-infliction interval of 6 days up to 1.5 months. Only the scar tissue of the oldest wound examined (wound age 7 months) revealed no increase in the number of positively staining fibroblasts. Therefore, positive results indicate a wound age of at least approximately 1.5 days and the lack of an increased number of positive fibroblastic cells in a sufficient number of specimens indicates at a wound age of less than 6 days, but cannot totally exclude longer post-infliction intervals
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